Page
34, Figure 1.9 (*)
New figure with arrangement of the graphics in a slightly different manner.
Page 41, Figure 1.16 (*)
New
figure with arrangement of the graphics in a slightly different manner.
The phasing of a hydrogen atom in the third cartoon orbital is changed.
Page
42, Line 7
Replace “C-C” with “C-O”
Page
49, Figure 1.22 (*)
New figure with phasing corrected.
Page
59
Line 7: Replace “A” with “i”
Line 17: Replace
“C-C-C” with “N-C-N”
Page 79
Line 7L Replace “-29.43” with “-29.9”
Page
96
several
changes in second paragraph:
Line 2: Replace -42.04 with –42.36
Line 6: Replace -42.04 with –42.36
Line 7: Replace –41.24 with –41.56
Line 9: Replace -42.04 with –42.36
Line 9: Replace –40.44 with –40.76
Page
110
Fifth full paragraph, line 3 replace “heptane” with “hexane”
Page
125
Fourth full paragraph, line 2 replace “stable” with “persistant”
Page
129
Fourth full paragraph, last line replace “Table 1.1” with “Table 1.4”
Page
141
Problem 34, second entry should be CH2CH3.
Page 148
Third line in parentheses, delete “=1”.
Page
283
Third
paragraph, first line, replace “pKas” with “acidities”.
Page
290
Second and third sentences on the page to now read “The lower the energy of
the orbitals containing the nucleophilic electrons, and the higher the energy of
the empty orbital that can accept the electrons, the “harder” the respective
base and acid. Lewis acids and
bases with low energy empty and high energy filled orbitals are considered
“soft”, respectively.
Page
312 (*)
New graphical insert correcting a mistake in wedges and dashes.
Page
315
Fifth paragraph, seventh line insert “(n=1 in this case” at the end of the
sentence containing “molecule” as the last word.
Page
361
First full paragraph, five lines from the bottom, delete “(R to I in each
case)”.
Page
367
Second full paragraph, second line, replace “7.17” with “7.16”.
Page
387
In
the Connections, the first chemical equation is missing a methyl group in the
first radical product shown.
Page
392
Eq. 7.55, should = 0, while 7.56 should not = 0.
Page 426
Third full paragraph, second line, replace “Figure 8.4B” with “Figure
8.5B”.
Last line of the
page, replace “Figure 8.4C” with “Figure 8.5C”.
Page
513
Line
seven, replace “Figure 9.9 A” with “Figure 9.9 C”.
Page
528
There should be no “o” superscripts on the Gibbs activation energies.
Page 532
Structure of pyridoxal is wrong, There should be a methylene between the
phosphate and the phenyl ring.
Page 707
Second paragraph, third line, replace “coordination” with “bonding”.
Page
727
First
line of section 12.2.4 to now read “There is an entire class of eliminations
that occur at metal centers where a group or atom from the ligand migrates to
the metal while at the same time an unsaturated system is produced (Eq.
12.34).”
Page
748
Problem 9, the “Cp2” is missing on the “Ti” of the product.
Page 809
Eq. 14.6, there should be a “2” exponent on the “h-bar”.
Page
810
Fifth
line from the bottom, insert “also called bra-ket,” in the parentheses
before “Eq. 14.10”.
Page
831
Figure 14.9, There should be a prime on the DE going up.
Figure
14.19, Delete the first sentence of the figure caption.
Page
851 (*)
Figure
14.22 has been replaced with one that has the correct phasings.
Page
904 (*)
Figure
15.16, replaced with a figure that put new dashes in part A.
Page 1028
In Figure 17.19 part C, replace “m-xylene” with “m-Xylylene”.
Page
1074
Problem K, should have a second step – “2) NaH”.
Back Inside Cover
The caption starting “Substituent effects on the …” should be on the next
page about the ESPs.
